Synthesis of an Aluminum Spirocyclic Hybrid with an Inorganic B2O3 and an Organic C3N2 Core

Synthesis of an Aluminum Spirocyclic Hybrid with an Inorganic B2O3 and an Organic C3N2 Core

The reaction of LAl (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) or LAlH2 with PhB(OH)2 yields the unprecedented spirocyclic LAl[(OBPh)2O] compound. The former reaction proceeds under hydrogen formation and simultaneous oxidation of the aluminum(I).

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Veröffentlicht in:Journal of the American Chemical Society 2006-09, Vol.128 (38), p.12406-12407
Hauptverfasser: Yang, Zhi, Ma, Xiaoli, Oswald, Rainer B, Roesky, Herbert W, Noltemeyer, Mathias
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
General and physical chemistry
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Zusammenfassung:The reaction of LAl (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) or LAlH2 with PhB(OH)2 yields the unprecedented spirocyclic LAl[(OBPh)2O] compound. The former reaction proceeds under hydrogen formation and simultaneous oxidation of the aluminum(I).
ISSN:0002-7863
1520-5126
DOI:10.1021/ja064035w