Efficient Synthesis of Functionalized Organozinc Compounds by the Direct Insertion of Zinc into Organic Iodides and Bromides

Insider dealing: A wide range of polyfunctional (hetero)aromatic and aliphatic zinc reagents can be easily prepared in THF. The compounds are formed by a Zn insertion reaction mediated by the addition of LiCl (see scheme; All=allyl).

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition 2006-09, Vol.45 (36), p.6040-6044
Hauptverfasser:	Krasovskiy, Arkady, Malakhov, Vladimir, Gavryushin, Andrei, Knochel, Paul
Format:	Artikel
Sprache:	eng
Schlagworte:	coupling homogeneous catalysis Hydrocarbons, Brominated - chemistry Hydrocarbons, Iodinated - chemistry insertion Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry organozinc compounds zinc Zinc - chemistry Zinc Compounds - chemical synthesis Zinc Compounds - chemistry
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Beschreibung
Zusammenfassung:	Insider dealing: A wide range of polyfunctional (hetero)aromatic and aliphatic zinc reagents can be easily prepared in THF. The compounds are formed by a Zn insertion reaction mediated by the addition of LiCl (see scheme; All=allyl).
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200601450