Chelated heteroatoms in polyoxometalates and the topological equivalence of [CoIII(en)] to type II cis-dioxometal centers. Synthesis and structure of [[Co(en)(mu-OH)2Co(en)}[PW10O37Co(en)]2]8- and [K subset[Co(en)WO4][WO(H2O)](PW9O34)2]12

Chelated heteroatoms in polyoxometalates and the topological equivalence of [CoIII(en)] to type II cis-dioxometal centers. Synthesis and structure of [[Co(en)(mu-OH)2Co(en)}[PW10O37Co(en)]2]8- and [K subset[Co(en)WO4][WO(H2O)](PW9O34)2]12

The first examples of polyoxometalate structures that incorporate embedded chelated heteroatoms point to new possibilities for stereochemical control of applications.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-12 (46), p.5760-5762
Hauptverfasser: Belai, Nebebech, Pope, Michael T
Format: Artikel
Sprache:eng
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Zusammenfassung:The first examples of polyoxometalate structures that incorporate embedded chelated heteroatoms point to new possibilities for stereochemical control of applications.
ISSN:1359-7345