A Bimetallic Complex Containing a Cyclopentadienyl-Annulated Imidazol-2-ylidene
A bimetallic carbene complex architecture that incorporates a cyclopentadienyl-annulated imidazol-2-ylidene moiety is characterized. The ligand architecture enables direct electronic interaction between the π- and σ-bonded metals. A preliminary example of aqueous Suzuki coupling employing a metalloc...
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| Veröffentlicht in: | Journal of the American Chemical Society 2005-11, Vol.127 (47), p.16400-16401 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A bimetallic carbene complex architecture that incorporates a cyclopentadienyl-annulated imidazol-2-ylidene moiety is characterized. The ligand architecture enables direct electronic interaction between the π- and σ-bonded metals. A preliminary example of aqueous Suzuki coupling employing a metallocene-fused imidazol-2-ylidene-derived catalyst is described. |
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| ISSN: | 0002-7863 1520-5126 |
| DOI: | 10.1021/ja055565f |