Synthesis of the C(43)−C(67) Fragment of Amphidinol 3

Synthesis of the C(43)−C(67) Fragment of Amphidinol 3

A synthesis of the C(43)−C(67) fragment of amphidinol 3 (AM3) has been accomplished by a route that features the use of a double allylboration reaction for synthesis of 1,5-diol 4b, which serves as a precursor to dihydropyran 11.

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Veröffentlicht in:Organic letters 2005-11, Vol.7 (24), p.5509-5512
Hauptverfasser: Hicks, Jacqueline D, Flamme, Eric M, Roush, William R
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols - chemical synthesis
Alkenes - chemical synthesis
Alkenes - chemistry
Animals
Boron Compounds - chemistry
Catalysis
Dinoflagellida - chemistry
Molecular Structure
Pyrans - chemical synthesis
Pyrans - chemistry
Stereoisomerism
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Zusammenfassung:A synthesis of the C(43)−C(67) fragment of amphidinol 3 (AM3) has been accomplished by a route that features the use of a double allylboration reaction for synthesis of 1,5-diol 4b, which serves as a precursor to dihydropyran 11.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol052322j