Synthesis and Structure of Sila-Adamantane

Synthesis and Structure of Sila-Adamantane

An organosilicon cage compound containing the sila-adamantane structural unit, which is the building block of crystalline silicon, was synthesized by the Lewis acid-catalyzed rearrangement reaction of a structural isomer.

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Bibliographische Detailangaben
Veröffentlicht in:Science (American Association for the Advancement of Science) 2005-11, Vol.310 (5749), p.825-825
Hauptverfasser: Fischer, Jelena, Baumgartner, Judith, Marschner, Christoph
Format: Artikel
Sprache:eng
Schlagworte:
Brevia
Chemical synthesis
Chemistry
Crystal lattices
Exact sciences and technology
Materials
Molecules
Organic Chemistry
Organometalloidal and organometallic compounds
Preparations and properties
Semiconductor industry
Si derivatives
Silicon
Silicon compounds
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Beschreibung
Zusammenfassung:An organosilicon cage compound containing the sila-adamantane structural unit, which is the building block of crystalline silicon, was synthesized by the Lewis acid-catalyzed rearrangement reaction of a structural isomer.
ISSN:0036-8075
1095-9203
DOI:10.1126/science.1118981