Discovery of a Family of Isopolyoxotungstates [H4W19O62]6− Encapsulating a {WO6} Moiety within a {W18} Dawson-like Cluster Cage

Discovery of a Family of Isopolyoxotungstates [H4W19O62]6− Encapsulating a {WO6} Moiety within a {W18} Dawson-like Cluster Cage

Caged up: A family of isopolyoxotungstate clusters of the form [H4W19O62]6− with a cluster cage (blue) identical to that of the Dawson‐type heteropolyacids (red) has been discovered. These comprise a single trigonal‐prismatic or octahedral {WO6}6− moiety in place of the two heteroanions found in the...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2006-07, Vol.45 (29), p.4798-4803
Hauptverfasser: Long, De-Liang, Kögerler, Paul, Parenty, Alexis D. C., Fielden, John, Cronin, Leroy
Format: Artikel
Sprache:eng
Schlagworte:
cluster compounds
electronic structure
polyoxometalates
self-assembly
tungsten
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Caged up: A family of isopolyoxotungstate clusters of the form [H4W19O62]6− with a cluster cage (blue) identical to that of the Dawson‐type heteropolyacids (red) has been discovered. These comprise a single trigonal‐prismatic or octahedral {WO6}6− moiety in place of the two heteroanions found in the Dawson structure.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200504600