Critical dynamics in a binary fluid: simulations and finite-size scaling

We report comprehensive simulations of the critical dynamics of a symmetric binary Lennard-Jones mixture near its consolute point. The self-diffusion coefficient exhibits no detectable anomaly. The data for the shear viscosity and the mutual-diffusion coefficient are fully consistent with the asympt...

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Veröffentlicht in:Physical review letters 2006-07, Vol.97 (2), p.025702-025702, Article 025702
Hauptverfasser: Das, Subir K, Fisher, Michael E, Sengers, Jan V, Horbach, Jürgen, Binder, Kurt
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Sprache:eng
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Zusammenfassung:We report comprehensive simulations of the critical dynamics of a symmetric binary Lennard-Jones mixture near its consolute point. The self-diffusion coefficient exhibits no detectable anomaly. The data for the shear viscosity and the mutual-diffusion coefficient are fully consistent with the asymptotic power laws and amplitudes predicted by renormalization-group and mode-coupling theories provided finite-size effects and the background contribution to the relevant Onsager coefficient are suitably accounted for. This resolves a controversy raised by recent molecular simulations.
ISSN:0031-9007
1079-7114
DOI:10.1103/physrevlett.97.025702