Very High Rate Enhancement of Benzyl Alcohol Oxidation by an Artificial Enzyme

Very High Rate Enhancement of Benzyl Alcohol Oxidation by an Artificial Enzyme

Promoting the atomic dialogue! At neutral pH and ambient temperature, a cyclodextrin‐derived ketone causes hydrogen peroxide and benzyl alcohols to meet in its active site and react up to 60 000 times faster than they do outside the cyclodextrin.

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Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2006-07, Vol.45 (28), p.4590-4593
Hauptverfasser: Marinescu, Lavinia G., Bols, Mikael
Format: Artikel
Sprache:eng
Schlagworte:
Benzyl Alcohol - chemistry
Benzyl Alcohol - metabolism
biomimetics
cyclodextrins
Enzymes - chemistry
Enzymes - metabolism
Hydrogen Peroxide - chemistry
Michaelis-Menten kinetics
Molecular Structure
Oxidation-Reduction
supramolecular chemistry
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Beschreibung
Zusammenfassung:Promoting the atomic dialogue! At neutral pH and ambient temperature, a cyclodextrin‐derived ketone causes hydrogen peroxide and benzyl alcohols to meet in its active site and react up to 60 000 times faster than they do outside the cyclodextrin.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200600812