Structure Elucidation of the Highly Active Titanosilicate Catalyst Ti-YNU-1

Between the sheets: The structure of the titanosilicate Ti‐YNU‐1 reveals a much larger spacing along the c axis between the MWW sheets than its lamellar precursor and 3D Ti‐MWW (see picture). Formation of twelve‐membered rings would explain this cell expansion, which results in increased steric acce...

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Veröffentlicht in:	Angewandte Chemie International Edition 2005-10, Vol.44 (41), p.6719-6723
Hauptverfasser:	Ruan, Juanfang, Wu, Peng, Slater, Ben, Terasaki, Osamu
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Sprache:	eng
Schlagworte:	layered compounds silicates structure elucidation titanates zeolite analogues
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description	Between the sheets: The structure of the titanosilicate Ti‐YNU‐1 reveals a much larger spacing along the c axis between the MWW sheets than its lamellar precursor and 3D Ti‐MWW (see picture). Formation of twelve‐membered rings would explain this cell expansion, which results in increased steric accessibility and may explain the higher catalytic activity of Ti‐YNU‐1 relative to other titanosilicates.
doi_str_mv	10.1002/anie.200501939
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subjects	layered compounds silicates structure elucidation titanates zeolite analogues
title	Structure Elucidation of the Highly Active Titanosilicate Catalyst Ti-YNU-1
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