Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes

Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes

Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine-olefin complexes, some of which are catalytically active for 1,4-additions.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-01 (32), p.3408-3410
Hauptverfasser: Douglas, Thomas M, Le Nôtre, Jérôme, Brayshaw, Simon K, Frost, Christopher G, Weller, Andrew S
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes - chemistry
Catalysis
Hydrogenation
Ketones - chemical synthesis
Ketones - chemistry
Ligands
Magnetic Resonance Spectroscopy
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Phosphines - chemistry
Rhodium - chemistry
Sensitivity and Specificity
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Beschreibung
Zusammenfassung:Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine-olefin complexes, some of which are catalytically active for 1,4-additions.
ISSN:1359-7345
1364-548X
DOI:10.1039/b608129k