Systems Chemistry: Kinetic and Computational Analysis of a Nearly Exponential Organic Replicator

Systems Chemistry: Kinetic and Computational Analysis of a Nearly Exponential Organic Replicator

Combining kinetic, structural, and computational studies on complex dynamic feedback systems may lead to the field of “systems chemistry”. The approach is exemplified by the analysis of a simple organic self‐replicating system that has the potential to express both homochiral autocatalysis and heter...

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Veröffentlicht in:Angewandte Chemie International Edition 2005-10, Vol.44 (41), p.6750-6755
Hauptverfasser: Kindermann, Maik, Stahl, Insa, Reimold, Malte, Pankau, Wolf Matthias, von Kiedrowski, Günter
Format: Artikel
Sprache:eng
Schlagworte:
chirality
computer chemistry
molecular modeling
supramolecular chemistry
template synthesis
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Zusammenfassung:Combining kinetic, structural, and computational studies on complex dynamic feedback systems may lead to the field of “systems chemistry”. The approach is exemplified by the analysis of a simple organic self‐replicating system that has the potential to express both homochiral autocatalysis and heterochiral cross‐catalysis (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200501527