Ortho-hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center

Ortho-hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center

The iron-assisted hydroxylation of benzoic acid to salicylic acid by 1/H2O2 has been achieved in good yield under mild conditions (where is [Fe(II)(BPMEN)(CH3CN)2](ClO4)2 and BPMEN =N,N'-dimethyl-N,N'-bis(2-pyridylmethyl)ethane-1,2-diamine); the product of this reaction is a novel mononucl...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-11 (42), p.5301-5303
Hauptverfasser: Taktak, Sonia, Flook, Margaret, Foxman, Bruce M, Que, Jr, Lawrence, Rybak-Akimova, Elena V
Format: Artikel
Sprache:eng
Schlagworte:
Benzoates - chemistry
Hydrogen Peroxide - chemistry
Hydroxylation
Models, Molecular
Molecular Structure
Nonheme Iron Proteins - chemistry
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Zusammenfassung:The iron-assisted hydroxylation of benzoic acid to salicylic acid by 1/H2O2 has been achieved in good yield under mild conditions (where is [Fe(II)(BPMEN)(CH3CN)2](ClO4)2 and BPMEN =N,N'-dimethyl-N,N'-bis(2-pyridylmethyl)ethane-1,2-diamine); the product of this reaction is a novel mononuclear iron(III) complex with a chelating salicylate.
ISSN:1359-7345
1364-548X
DOI:10.1039/b508004e