Hypervalent Iodine Goes Catalytic

A dash of iodine: Different reactions relying on the power of hypervalent iodine reagents can now be performed with catalytic amounts of these compounds and a stoichiometric oxidant. Oxidations of alcohols, α‐functionalizations of ketones, and spirocyclizations of phenol derivatives are possible.

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Veröffentlicht in:Angewandte Chemie International Edition 2006-07, Vol.45 (27), p.4402-4404
Hauptverfasser: Richardson, Robert D., Wirth, Thomas
Format: Artikel
Sprache:eng
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Zusammenfassung:A dash of iodine: Different reactions relying on the power of hypervalent iodine reagents can now be performed with catalytic amounts of these compounds and a stoichiometric oxidant. Oxidations of alcohols, α‐functionalizations of ketones, and spirocyclizations of phenol derivatives are possible.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200601817