Hypervalent Iodine Goes Catalytic
A dash of iodine: Different reactions relying on the power of hypervalent iodine reagents can now be performed with catalytic amounts of these compounds and a stoichiometric oxidant. Oxidations of alcohols, α‐functionalizations of ketones, and spirocyclizations of phenol derivatives are possible.
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Veröffentlicht in: | Angewandte Chemie International Edition 2006-07, Vol.45 (27), p.4402-4404 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | A dash of iodine: Different reactions relying on the power of hypervalent iodine reagents can now be performed with catalytic amounts of these compounds and a stoichiometric oxidant. Oxidations of alcohols, α‐functionalizations of ketones, and spirocyclizations of phenol derivatives are possible. |
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ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.200601817 |