Positional Control of Encapsulated Atoms Inside a Fullerene Cage by Exohedral Addition

The exohedrally functionalized derivative of endohedral metallofullerene, Ce2@C80(Mes2SiCH2SiMes2), was successfully synthesized and fully characterized. X-ray crystallographic and NMR spectroscopic analyses reveal that the free random motion of two metal atoms in Ce2@C80 is controlled inside the ca...

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Veröffentlicht in:	Journal of the American Chemical Society 2005-10, Vol.127 (42), p.14570-14571
Hauptverfasser:	Yamada, Michio, Nakahodo, Tsukasa, Wakahara, Takatsugu, Tsuchiya, Takahiro, Maeda, Yutaka, Akasaka, Takeshi, Kako, Masahiro, Yoza, Kenji, Horn, Ernst, Mizorogi, Naomi, Kobayashi, Kaoru, Nagase, Shigeru
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon Isotopes Cerium - chemistry Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Fullerenes - chemistry Inorganic chemistry and origins of life Inorganic compounds Kinetics and mechanism of reactions Magnetic Resonance Spectroscopy - methods Magnetic Resonance Spectroscopy - standards Miscellaneous Models, Molecular Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Physics Reference Standards Structure of solids and liquids crystallography Structure of specific crystalline solids
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Zusammenfassung:	The exohedrally functionalized derivative of endohedral metallofullerene, Ce2@C80(Mes2SiCH2SiMes2), was successfully synthesized and fully characterized. X-ray crystallographic and NMR spectroscopic analyses reveal that the free random motion of two metal atoms in Ce2@C80 is controlled inside the cage by exohedral chemical functionalization.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja054346r