Two-Step Spin Conversion in a Cyanide-Bridged Ferrous Square

Spinning out: A cyanide‐bridged molecular square (see picture) has been isolated and found to undergo thermally induced, two‐step spin crossover. Molecules with more than one spin‐crossover site are suitable building blocks for multistepped molecular switches.

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Veröffentlicht in:Angewandte Chemie International Edition 2005-10, Vol.44 (40), p.6484-6487
Hauptverfasser: Nihei, Masayuki, Ui, Mayumi, Yokota, Mizuho, Han, Lingqin, Maeda, Atsushi, Kishida, Hideo, Okamoto, Hiroshi, Oshio, Hiroki
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Sprache:eng
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Zusammenfassung:Spinning out: A cyanide‐bridged molecular square (see picture) has been isolated and found to undergo thermally induced, two‐step spin crossover. Molecules with more than one spin‐crossover site are suitable building blocks for multistepped molecular switches.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200502216