A missing allene of heavy Group 14 elements: 2-germadisilaallene

A missing allene of heavy Group 14 elements: 2-germadisilaallene

The first stable 2-germadisilaallene was synthesized by the reduction of a 2 ratio 1 mixture of a stable dialkylsilylene and dichlorogermylene-dioxane complex with KC8; the 2-germadisilaallene showed dynamic disorder similar to the corresponding trisilaallene in the solid state.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-11 (41), p.5190-5192
Hauptverfasser: Iwamoto, Takeaki, Abe, Takashi, Kabuto, Chizuko, Kira, Mitsuo
Format: Artikel
Sprache:eng
Schlagworte:
Alkadienes - chemistry
Crystallography, X-Ray
Germanium - chemistry
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Silicon - chemistry
Stereoisomerism
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Zusammenfassung:The first stable 2-germadisilaallene was synthesized by the reduction of a 2 ratio 1 mixture of a stable dialkylsilylene and dichlorogermylene-dioxane complex with KC8; the 2-germadisilaallene showed dynamic disorder similar to the corresponding trisilaallene in the solid state.
ISSN:1359-7345
1364-548X
DOI:10.1039/b509878e