Charge‐Transfer Isomers and Mixed‐Valence Properties

Charge‐Transfer Isomers and Mixed‐Valence Properties

The unusual suspects: By using a series of ruthenium clusters of the type [{Ru3O(μ‐CH3COO)6(CO)L′}(μ‐L){Ru3O(μ‐CH3COO)6(CO)L′′}] (see picture) it has been possible to identify the existence of charge‐transfer isomers and establish them as identifiable chemical entities that exist in dynamic equilibr...

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Veröffentlicht in:Angewandte Chemie International Edition 2005-10, Vol.44 (40), p.6452-6454
1. Verfasser: Crutchley, Robert J.
Format: Artikel
Sprache:eng
Schlagworte:
bridging ligands
charge‐transfer isomers
cluster compounds
mixed‐valence compounds
ruthenium
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Beschreibung
Zusammenfassung:The unusual suspects: By using a series of ruthenium clusters of the type [{Ru3O(μ‐CH3COO)6(CO)L′}(μ‐L){Ru3O(μ‐CH3COO)6(CO)L′′}] (see picture) it has been possible to identify the existence of charge‐transfer isomers and establish them as identifiable chemical entities that exist in dynamic equilibrium.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200501598