The first A2B2-heterometal ferrimagnetic chain. Structures and magnetic properties of polymeric [Gd2Cu2]n and the corresponding monomer

One-dimensional polymeric complexes consisting of alternating dicopper(II) and digadolinium(III) units exhibited ferrimagnetic behavior which was ascribable to antiferromagnetic coupling across the oximate N-O bridges between the high-spin homodinuclear units.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2005-11 (41), p.5223-5225
Hauptverfasser:	Ueki, Sohei, Kobayashi, Yasuko, Ishida, Takayuki, Nogami, Takashi
Format:	Artikel
Sprache:	eng
Schlagworte:	Copper - chemistry Crystallography, X-Ray Gadolinium - chemistry Magnetics Models, Molecular Molecular Structure Organometallic Compounds - chemistry Temperature
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	One-dimensional polymeric complexes consisting of alternating dicopper(II) and digadolinium(III) units exhibited ferrimagnetic behavior which was ascribable to antiferromagnetic coupling across the oximate N-O bridges between the high-spin homodinuclear units.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/b511361j