Synthesis and characterization of side-bound aryldiazo and end-bound nitrosyl complexes of nickel
Structural characterization of a nickel aryldiazo complex supported by the bulky 1,2-bis(di-tert-butylphosphino)ethane ligand reveals square-planar Ni geometry and an unusual side-on coordination mode for the N2R moiety, while the related nitrosyl complex displays trigonal-planar geometry at Ni and...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2005-10 (40), p.5091-5093 |
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| container_issue | 40 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Iluc, Vlad M Miller, Alexander J M Hillhouse, Gregory L |
| description | Structural characterization of a nickel aryldiazo complex supported by the bulky 1,2-bis(di-tert-butylphosphino)ethane ligand reveals square-planar Ni geometry and an unusual side-on coordination mode for the N2R moiety, while the related nitrosyl complex displays trigonal-planar geometry at Ni and end-on coordination of the NO ligand. |
| doi_str_mv | 10.1039/b510131j |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2005-10 (40), p.5091-5093 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_68686448 |
| source | MEDLINE; Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Azo Compounds - chemical synthesis Azo Compounds - chemistry Models, Molecular Molecular Conformation Nickel - chemistry Nitrogen - chemistry |
| title | Synthesis and characterization of side-bound aryldiazo and end-bound nitrosyl complexes of nickel |
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