Synthesis and characterization of side-bound aryldiazo and end-bound nitrosyl complexes of nickel

Synthesis and characterization of side-bound aryldiazo and end-bound nitrosyl complexes of nickel

Structural characterization of a nickel aryldiazo complex supported by the bulky 1,2-bis(di-tert-butylphosphino)ethane ligand reveals square-planar Ni geometry and an unusual side-on coordination mode for the N2R moiety, while the related nitrosyl complex displays trigonal-planar geometry at Ni and...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-10 (40), p.5091-5093
Hauptverfasser: Iluc, Vlad M, Miller, Alexander J M, Hillhouse, Gregory L
Format: Artikel
Sprache:eng
Schlagworte:
Azo Compounds - chemical synthesis
Azo Compounds - chemistry
Models, Molecular
Molecular Conformation
Nickel - chemistry
Nitrogen - chemistry
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Zusammenfassung:Structural characterization of a nickel aryldiazo complex supported by the bulky 1,2-bis(di-tert-butylphosphino)ethane ligand reveals square-planar Ni geometry and an unusual side-on coordination mode for the N2R moiety, while the related nitrosyl complex displays trigonal-planar geometry at Ni and end-on coordination of the NO ligand.
ISSN:1359-7345
1364-548X
DOI:10.1039/b510131j