CH Activation with an O-Donor Iridium−Methoxo Complex

A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometric, intermolecular C−H activation of benzene with co-generation of methanol and the iridium−phenyl complex.

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Journal of the American Chemical Society 2005-10, Vol.127 (41), p.14172-14173
Hauptverfasser:	Tenn, William J, Young, Kenneth J. H, Bhalla, Gaurav, Oxgaard, Jonas, Goddard, William A, Periana, Roy A
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzene - chemistry Catalysis Chemistry Exact sciences and technology Inorganic chemistry and origins of life Iridium - chemistry Kinetics and mechanism of reactions Methanol - chemistry Molecular Conformation Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxidation-Reduction Oxygen - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometric, intermolecular C−H activation of benzene with co-generation of methanol and the iridium−phenyl complex.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja051497l