The Internuclear Potential, Electronic Structure, and Chemical Bond of Tellurium Selenide

The Internuclear Potential, Electronic Structure, and Chemical Bond of Tellurium Selenide

Joining the jet set: High‐resolution, pure rotational spectra are obtained from a supersonic jet of TeSe prepared by laser ablation. The spectra give access to the internuclear potential, electronic structure (see picture), and details of the chemical bond of the first intermetallic 3Σ compound obse...

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Veröffentlicht in:Angewandte Chemie International Edition 2005-10, Vol.44 (39), p.6311-6315
Hauptverfasser: Banser, Deike, Schnell, Melanie, Grabow, Jens-Uwe, Cocinero, Emilio J., Lesarri, Alberto, Alonso, José L.
Format: Artikel
Sprache:eng
Schlagworte:
Born-Oppenheimer breakdown
chalcogens
laser ablation
rotational spectroscopy
supersonic jets
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Zusammenfassung:Joining the jet set: High‐resolution, pure rotational spectra are obtained from a supersonic jet of TeSe prepared by laser ablation. The spectra give access to the internuclear potential, electronic structure (see picture), and details of the chemical bond of the first intermetallic 3Σ compound observed by microwave spectroscopy.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200501658