Selective Nucleation and Growth of Metal−Organic Open Framework Thin Films on Patterned COOH/CF3-Terminated Self-Assembled Monolayers on Au(111)

Selective Nucleation and Growth of Metal−Organic Open Framework Thin Films on Patterned COOH/CF3-Terminated Self-Assembled Monolayers on Au(111)

Metal−Organic open Framework coordination polymers (MOFs) are a fascinating class of materials. We demonstrate the selective growth of patterned thin films of MOF-5 and the subsequent loading with a palladium organic compound, which acts as a precursor for the deposition of palladium nanoclusters in...

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Veröffentlicht in:Journal of the American Chemical Society 2005-10, Vol.127 (40), p.13744-13745
Hauptverfasser: Hermes, Stephan, Schröder, Felicitas, Chelmowski, Rolf, Wöll, Christof, Fischer, Roland A
Format: Artikel
Sprache:eng
Schlagworte:
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Gold - chemistry
Growth from solutions
Materials science
Membranes, Artificial
Methods of crystal growth
physics of crystal growth
Models, Molecular
Organometallic Compounds - chemistry
Particle Size
Physics
Surface Properties
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Zusammenfassung:Metal−Organic open Framework coordination polymers (MOFs) are a fascinating class of materials. We demonstrate the selective growth of patterned thin films of MOF-5 and the subsequent loading with a palladium organic compound, which acts as a precursor for the deposition of palladium nanoclusters inside the cavities of the MOF-5 material.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja053523l