Solvothermal in Situ Ligand Synthesis through Disulfide Cleavage:  3D (3,4)-Connected and 2D Square-Grid-Type Coordination Polymers

Solvothermal in Situ Ligand Synthesis through Disulfide Cleavage:  3D (3,4)-Connected and 2D Square-Grid-Type Coordination Polymers

Two novel coordination polymers, Cu3(4-pyt)3 (1) and Co(4-pyt)2 (2) (4-pyt = pyridine-4-thiolate), have been synthesized by in situ generation of a 4-pyt ligand from a 4,4‘-dithiodipyridine precursor through reductive cleavage of the disulfide bond under solvothermal conditions. 1 and 2 exhibit a th...

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Veröffentlicht in:Inorganic chemistry 2006-07, Vol.45 (15), p.5736-5738
Hauptverfasser: Han, Lei, Bu, Xianhui, Zhang, Qichun, Feng, Pingyun
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry, Inorganic - methods
Disulfides - chemistry
Hot Temperature
Ligands
Models, Chemical
Models, Molecular
Molecular Conformation
Polymers - chemistry
Spectrophotometry, Ultraviolet
Sulfides - chemistry
Temperature
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Zusammenfassung:Two novel coordination polymers, Cu3(4-pyt)3 (1) and Co(4-pyt)2 (2) (4-pyt = pyridine-4-thiolate), have been synthesized by in situ generation of a 4-pyt ligand from a 4,4‘-dithiodipyridine precursor through reductive cleavage of the disulfide bond under solvothermal conditions. 1 and 2 exhibit a three-dimensional (3,4)-connected network and a two-dimensional square-grid-type structure, respectively.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic0608041