Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer

Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer

The facile conversion of M−R to M−OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a Baeyer−Villiger-type pathway involving a nonredox, electrophilic, O-atom insertion in reactions with non-peroxo O-donors.

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Veröffentlicht in:Journal of the American Chemical Society 2006-07, Vol.128 (28), p.9018-9019
Hauptverfasser: Conley, Brian L, Ganesh, Somesh K, Gonzales, Jason M, Tenn, William J, Young, Kenneth J. H, Oxgaard, Jonas, Goddard, William A, Periana, Roy A
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
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Zusammenfassung:The facile conversion of M−R to M−OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a Baeyer−Villiger-type pathway involving a nonredox, electrophilic, O-atom insertion in reactions with non-peroxo O-donors.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja062417w