Lewis Acid-Assisted Nucleophilic Substitution of Fullerene Epoxide

A 1,4-bis(phenyl)-1,4-dihydro[60]fullerene resulting from an efficient nucleophilic substitution has been obtained by reaction of a fullerene epoxide, C60O, with nucleophilic aromatic compounds in the presence of boron trifluoride etherate as a Lewis acid.

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Bibliographische Detailangaben
Veröffentlicht in:	Organic letters 2006-07, Vol.8 (15), p.3203-3205
Hauptverfasser:	Tajima, Yusuke, Hara, Takumi, Honma, Takeshi, Matsumoto, Shiro, Takeuchi, Kazuo
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A 1,4-bis(phenyl)-1,4-dihydro[60]fullerene resulting from an efficient nucleophilic substitution has been obtained by reaction of a fullerene epoxide, C60O, with nucleophilic aromatic compounds in the presence of boron trifluoride etherate as a Lewis acid.
ISSN:	1523-7060 1523-7052
DOI:	10.1021/ol0610183