Total Synthesis of the Marine Natural Product (−)-Clavosolide A

The total synthesis of the marine metabolite clavosolide A is reported which confirms the structure and absolute configuration of the natural product as the symmetrical diolide glycosylated by permethylated d-xylose moieties, 2.

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Bibliographische Detailangaben
Veröffentlicht in:	Organic letters 2006-07, Vol.8 (15), p.3319-3322
Hauptverfasser:	Barry, Conor S, Elsworth, Jon D, Seden, Peter T, Bushby, Nick, Harding, John R, Alder, Roger W, Willis, Christine L
Format:	Artikel
Sprache:	eng
Schlagworte:	Biological Products - chemical synthesis Biological Products - chemistry Catalysis Macrolides - chemical synthesis Macrolides - chemistry Marine Biology Molecular Structure Stereoisomerism
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Beschreibung
Zusammenfassung:	The total synthesis of the marine metabolite clavosolide A is reported which confirms the structure and absolute configuration of the natural product as the symmetrical diolide glycosylated by permethylated d-xylose moieties, 2.
ISSN:	1523-7060 1523-7052
DOI:	10.1021/ol0611705