Air-Stable Racemization Catalyst for Dynamic Kinetic Resolution of Secondary Alcohols at Room Temperature

Air-Stable Racemization Catalyst for Dynamic Kinetic Resolution of Secondary Alcohols at Room Temperature

A novel racemization catalyst was synthesized for the dynamic kinetic resolution (DKR) of alcohols with a lipase at room temperature in the air. Furthermore, a polymer-supported derivative was also synthesized and tested as a recyclable catalyst for the aerobic DKR of alcohols.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2005-09, Vol.7 (20), p.4523-4526
Hauptverfasser: Kim, Namdu, Ko, Soo-Byung, Kwon, Min Serk, Kim, Mahn-Joo, Park, Jaiwook
Format: Artikel
Sprache:eng
Schlagworte:
Air
Alcohols - chemistry
Benzyl Alcohols - chemistry
Catalysis
Isomerism
Kinetics
Molecular Structure
Ruthenium - chemistry
Temperature
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A novel racemization catalyst was synthesized for the dynamic kinetic resolution (DKR) of alcohols with a lipase at room temperature in the air. Furthermore, a polymer-supported derivative was also synthesized and tested as a recyclable catalyst for the aerobic DKR of alcohols.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol051889x