Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation

Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation

A mononuclear nonheme ferric-peroxo complex bearing a macrocyclic tetradentate N4 ligand, [(TMC)Fe(III)-O2]+, was prepared and used in mechanistic studies of aldehyde deformylation; a catalytic aldehyde deformylation by a nonheme iron(II) complex, [Fe(II)(TMC)]2+, and molecular oxygen is reported as...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-09 (36), p.4529-4531
Hauptverfasser: Annaraj, Jamespandi, Suh, Yumi, Seo, Mi Sook, Kim, Sun Ok, Nam, Wonwoo
Format: Artikel
Sprache:eng
Schlagworte:
Aldehydes - chemistry
Catalysis
Ferric Compounds - chemical synthesis
Ferric Compounds - chemistry
Formates - chemistry
Oxygen - chemistry
Porphyrins - chemistry
Spectrophotometry, Ultraviolet
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Zusammenfassung:A mononuclear nonheme ferric-peroxo complex bearing a macrocyclic tetradentate N4 ligand, [(TMC)Fe(III)-O2]+, was prepared and used in mechanistic studies of aldehyde deformylation; a catalytic aldehyde deformylation by a nonheme iron(II) complex, [Fe(II)(TMC)]2+, and molecular oxygen is reported as well.
ISSN:1359-7345
1364-548X
DOI:10.1039/b505562h