Lewis Acid Adducts of [PCl2N]3

Lewis Acid Adducts of [PCl2N]3

Reaction of aluminum trichloride or gallium trichloride with the extremely weak base hexachlorotriphosphazene gives adducts in which the group 13 element is bound to a phosphazene nitrogen atom. In solution, the adducts exhibit fluxional behavior. The phosphazene ring of the adducts is distorted int...

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Veröffentlicht in:Inorganic chemistry 2005-09, Vol.44 (19), p.6518-6520
Hauptverfasser: Heston, Amy J, Panzner, Matthew J, Youngs, Wiley J, Tessier, Claire A
Format: Artikel
Sprache:eng
Schlagworte:
Acids - chemistry
Models, Molecular
Molecular Structure
Organophosphorus Compounds - chemistry
Polymers - chemistry
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Zusammenfassung:Reaction of aluminum trichloride or gallium trichloride with the extremely weak base hexachlorotriphosphazene gives adducts in which the group 13 element is bound to a phosphazene nitrogen atom. In solution, the adducts exhibit fluxional behavior. The phosphazene ring of the adducts is distorted into a slight chair conformation.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic050974y