Asymmetric synthesis of (+)-cis-nemorensic acid from a chiral Diels-Alder adduct of 2,5-dimethylfuran

Asymmetric synthesis of (+)-cis-nemorensic acid from a chiral Diels-Alder adduct of 2,5-dimethylfuran

(+)-cis-Nemorensic acid was synthesized from a chiral Diels-Alder adduct prepared by a catalytic enantioselective Diels-Alder reaction with 2,5-dimethylfuran and 2,2,2-trifluoroethyl acrylate.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007-01 (47), p.5064-5065
Hauptverfasser: Sim, Jae Yi, Hwang, Geum-Sook, Kim, Kyung Hwa, Ko, Eun Mi, Ryu, Do Hyun
Format: Artikel
Sprache:eng
Schlagworte:
Furans - chemical synthesis
Furans - chemistry
Models, Molecular
Molecular Structure
Pyrrolizidine Alkaloids - chemical synthesis
Pyrrolizidine Alkaloids - chemistry
Stereoisomerism
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Beschreibung
Zusammenfassung:(+)-cis-Nemorensic acid was synthesized from a chiral Diels-Alder adduct prepared by a catalytic enantioselective Diels-Alder reaction with 2,5-dimethylfuran and 2,2,2-trifluoroethyl acrylate.
ISSN:1359-7345
1364-548X
DOI:10.1039/b710537a