Transition Metal-Catalyzed Synthesis of Pyrroles from Dienyl Azides

Transition Metal-Catalyzed Synthesis of Pyrroles from Dienyl Azides

A range of 2,5-disubstituted and 2,4,5-trisubstituted pyrroles can be synthesized from dienyl azides at room temperature using catalytic amounts of ZnI2 or Rh2(O2CC3F7)4.

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Veröffentlicht in:Organic letters 2007-12, Vol.9 (25), p.5191-5194
Hauptverfasser: Dong, Huijun, Shen, Meihua, Redford, Joanne E, Stokes, Benjamin J, Pumphrey, Ashley L, Driver, Tom G
Format: Artikel
Sprache:eng
Schlagworte:
Azides - chemistry
Catalysis
Magnetic Resonance Spectroscopy
Molecular Structure
Pyrroles - chemical synthesis
Pyrroles - chemistry
Transition Elements - chemistry
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Beschreibung
Zusammenfassung:A range of 2,5-disubstituted and 2,4,5-trisubstituted pyrroles can be synthesized from dienyl azides at room temperature using catalytic amounts of ZnI2 or Rh2(O2CC3F7)4.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol702262f