Palladium-NHC complexes do catalyse the diboration of alkenes: mechanistic insights

Novel catalytic activation of the B-B bond by palladium(II)-NHC complexes in presence of a mild base (NaOAc) and an excess of diboron reagent enables chemoselective 1,2-diboration of alkenes, suggesting the heterolytic cleavage of diboron rather than oxidative addition of a B-B bond to the metal.

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2007-01 (32), p.3380-3382
Hauptverfasser:	Lillo, Vanesa, Mas-Marzá, Elena, Segarra, Anna M, Carbó, Jorge J, Bo, Carles, Peris, Eduardo, Fernandez, Elena
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Novel catalytic activation of the B-B bond by palladium(II)-NHC complexes in presence of a mild base (NaOAc) and an excess of diboron reagent enables chemoselective 1,2-diboration of alkenes, suggesting the heterolytic cleavage of diboron rather than oxidative addition of a B-B bond to the metal.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/b705197b