Catalytic enantioselective diboration, disilation and silaboration: new opportunities for asymmetric synthesis

This article summarizes recent developments in the area of catalytic enantioselective reactions of unsaturated organic substrates with diboron, silylboron, and disilane reagents. These reactions provide new routes to the functionalization of prochiral substrates and therefore offer new strategies in...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007-01 (45), p.4717-4725
Hauptverfasser: Burks, Heather E, Morken, James P
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creator Burks, Heather E
Morken, James P
description This article summarizes recent developments in the area of catalytic enantioselective reactions of unsaturated organic substrates with diboron, silylboron, and disilane reagents. These reactions provide new routes to the functionalization of prochiral substrates and therefore offer new strategies in asymmetric organic synthesis.
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source Royal Society of Chemistry Journals Archive (1841-2007); MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Alkenes - chemistry
Boranes - chemistry
Catalysis
Ketones - chemistry
Silanes - chemistry
Stereoisomerism
title Catalytic enantioselective diboration, disilation and silaboration: new opportunities for asymmetric synthesis
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