Catalytic enantioselective diboration, disilation and silaboration: new opportunities for asymmetric synthesis

Catalytic enantioselective diboration, disilation and silaboration: new opportunities for asymmetric synthesis

This article summarizes recent developments in the area of catalytic enantioselective reactions of unsaturated organic substrates with diboron, silylboron, and disilane reagents. These reactions provide new routes to the functionalization of prochiral substrates and therefore offer new strategies in...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007-01 (45), p.4717-4725
Hauptverfasser: Burks, Heather E, Morken, James P
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes - chemistry
Boranes - chemistry
Catalysis
Ketones - chemistry
Silanes - chemistry
Stereoisomerism
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Beschreibung
Zusammenfassung:This article summarizes recent developments in the area of catalytic enantioselective reactions of unsaturated organic substrates with diboron, silylboron, and disilane reagents. These reactions provide new routes to the functionalization of prochiral substrates and therefore offer new strategies in asymmetric organic synthesis.
ISSN:1359-7345
1364-548X
DOI:10.1039/b707779c