Dynamic helicity inversion in an octahedral cobalt(II) complex system via solvato-diastereomerism

The helical sense of a mononuclear Co(II) complex with an amino acid-based chiral tetradentate ligand was dynamically inverted by changing the solvent component.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2005-09 (34), p.4291-4293
Hauptverfasser:	Miyake, Hiroyuki, Sugimoto, Hideki, Tamiaki, Hitoshi, Tsukube, Hiroshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Amino Acids - chemistry Circular Dichroism Hydrogen-Ion Concentration Ligands Magnetic Resonance Spectroscopy Molecular Conformation Organometallic Compounds - chemistry Solvents Stereoisomerism
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The helical sense of a mononuclear Co(II) complex with an amino acid-based chiral tetradentate ligand was dynamically inverted by changing the solvent component.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/b506130j