Alternating Hydrophilic and Hydrophobic Pockets in the Channel Structures of Organostannoxane Prismanes: Preferential Confinement of Guest Molecules

A hydroxyl-rich hexameric organooxotin prismane has been prepared by reaction of n-BuSn(O)OH with 9-hydroxy-9-fluorenecarboxylic acid. The supramolecular structure of this cage shows channels with hydrophobic and hydrophilic segments, which selectively entrap guest molecules.

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Journal of the American Chemical Society 2005-08, Vol.127 (33), p.11556-11557
Hauptverfasser:	Chandrasekhar, Vadapalli, Thilagar, Pakkirisamy, Bickley, James F, Steiner, Alexander
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Condensed matter: structure, mechanical and thermal properties Coordination compounds Crystallography, X-Ray Exact sciences and technology Hydrogen Bonding Inorganic chemistry and origins of life Inorganic compounds Metal complexes Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids Tin - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	A hydroxyl-rich hexameric organooxotin prismane has been prepared by reaction of n-BuSn(O)OH with 9-hydroxy-9-fluorenecarboxylic acid. The supramolecular structure of this cage shows channels with hydrophobic and hydrophilic segments, which selectively entrap guest molecules.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja052776b