Structural Competition between Hydrogen Bonds and Halogen Bonds

Structural Competition between Hydrogen Bonds and Halogen Bonds

The molecules presented here provide a test-bed for competitive supramolecular chemistry, and on the basis of five crystal structures a ranking of the relative structural importance and influence of competing weak/strong hydrogen bonds and weak/strong halogen bonds has been achieved.

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Veröffentlicht in:Journal of the American Chemical Society 2007-11, Vol.129 (45), p.13772-13773
Hauptverfasser: Aakeröy, Christer B, Fasulo, Meg, Schultheiss, Nate, Desper, John, Moore, Curtis
Format: Artikel
Sprache:eng
Schlagworte:
Crystallography, X-Ray
Hydrocarbons, Halogenated - chemistry
Hydrogen Bonding
Models, Molecular
Molecular Structure
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Beschreibung
Zusammenfassung:The molecules presented here provide a test-bed for competitive supramolecular chemistry, and on the basis of five crystal structures a ranking of the relative structural importance and influence of competing weak/strong hydrogen bonds and weak/strong halogen bonds has been achieved.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja073201c