Electrochemical Behavior of an Aminotrithioether Ligand:  Copper(II)-Mediated Oxidative C−C Bond Formation

Electrochemical Behavior of an Aminotrithioether Ligand:  Copper(II)-Mediated Oxidative C−C Bond Formation

A neutral aminotrithioether interacts with CuI, generating a coordination polymer in the solid state. Electrochemical studies indicate that the ligand is prone to oxidation by CuII, which results in a novel C−C bond formation reaction.

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Veröffentlicht in:Inorganic chemistry 2007-11, Vol.46 (23), p.9510-9512
Hauptverfasser: Huerta, Raúl, Flores-Figueroa, Aarón, Ugalde-Saldívar, Víctor M, Castillo, Ivan
Format: Artikel
Sprache:eng
Schlagworte:
Carbon - chemistry
Crystallography, X-Ray
Electrochemistry
Ethers - chemistry
Ligands
Models, Molecular
Oxidation-Reduction
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Beschreibung
Zusammenfassung:A neutral aminotrithioether interacts with CuI, generating a coordination polymer in the solid state. Electrochemical studies indicate that the ligand is prone to oxidation by CuII, which results in a novel C−C bond formation reaction.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic7009429