Homoleptic Silver(I) Acetylene Complexes

Homoleptic Silver(I) Acetylene Complexes

Hanging on to acetylene: The solid‐state structures of the first homoleptic metal HCCH complexes [M(C2H2)x]n (M=any metal; n, x=any number), salts of [Ag(η2‐C2H2)n]+ (n=3,4), are described (see picture). The electronic structure of a [Ag(η2‐C2H2)] model complex has been investigated by experimental...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2007-01, Vol.46 (43), p.8295-8298
Hauptverfasser: Reisinger, Andreas, Trapp, Nils, Krossing, Ingo, Altmannshofer, Sandra, Herz, Verena, Presnitz, Manuel, Scherer, Wolfgang
Format: Artikel
Sprache:eng
Schlagworte:
ab initio calculations
alkynes
charge density
silver
weakly coordinating anions
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Zusammenfassung:Hanging on to acetylene: The solid‐state structures of the first homoleptic metal HCCH complexes [M(C2H2)x]n (M=any metal; n, x=any number), salts of [Ag(η2‐C2H2)n]+ (n=3,4), are described (see picture). The electronic structure of a [Ag(η2‐C2H2)] model complex has been investigated by experimental charge‐density studies.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200702688