N-Heterocyclic carbene adducts of orthopalladated triarylphosphite complexes

Carbene adducts of orthopalladated triarylphosphite complexes have been synthesised and characterised. The structures of three of these complexes were determined by single-crystal X-ray analysis. The complexes are active in the Suzuki coupling of a range of aryl bromide substrates.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2005-08 (16), p.2774-2779
Hauptverfasser: Bedford, Robin B, Betham, Michael, Blake, Michael E, Frost, Robert M, Horton, Peter N, Hursthouse, Michael B, López-Nicolás, Rosa-María
Format: Artikel
Sprache:eng
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Zusammenfassung:Carbene adducts of orthopalladated triarylphosphite complexes have been synthesised and characterised. The structures of three of these complexes were determined by single-crystal X-ray analysis. The complexes are active in the Suzuki coupling of a range of aryl bromide substrates.
ISSN:1477-9226
1477-9234
DOI:10.1039/b506286a