Nickel(0) Triethyl Phosphite Complex-Catalyzed Allylic Substitution with Retention of Regio- and Stereochemistry

Nickel(0) Triethyl Phosphite Complex-Catalyzed Allylic Substitution with Retention of Regio- and Stereochemistry

Nickel(0) triethyl phosphite complex-promoted reaction of allylic acetates with thiols produced allylic sulfides with retention of configuration without allylic rearrangement. A similar reaction of allylic acetates with alcohols and phenols also proceeded with retention of regio- and stereochemistry...

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Veröffentlicht in:Organic letters 2007-10, Vol.9 (22), p.4603-4606
Hauptverfasser: Yatsumonji, Yasutaka, Ishida, Yusuke, Tsubouchi, Akira, Takeda, Takeshi
Format: Artikel
Sprache:eng
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Zusammenfassung:Nickel(0) triethyl phosphite complex-promoted reaction of allylic acetates with thiols produced allylic sulfides with retention of configuration without allylic rearrangement. A similar reaction of allylic acetates with alcohols and phenols also proceeded with retention of regio- and stereochemistry.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol702122d