A General Method for the Preparation of Ethers Using Water-Resistant Solid Lewis Acids

A General Method for the Preparation of Ethers Using Water-Resistant Solid Lewis Acids

This most ethereal of cascades: Water‐resistant single isolated Lewis acids within the framework of molecular sieves act as excellent general catalysts for the synthesis of ethers (see scheme). On this basis, an environmentally friendly process has been developed for the preparation of fine chemical...

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Veröffentlicht in:Angewandte Chemie International Edition 2007-01, Vol.46 (1-2), p.298-300
Hauptverfasser: Corma, Avelino, Renz, Michael
Format: Artikel
Sprache:eng
Schlagworte:
Acids - chemistry
Alcohol Oxidoreductases - chemistry
cascade reactions
Catalysis
etherification
Ethers - chemical synthesis
Ethers - chemistry
Lewis acids
Molecular Structure
Organometallic Compounds - chemistry
Stereoisomerism
tin
Tin - chemistry
Titanium - chemistry
Water - chemistry
zeolites
Zirconium - chemistry
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Beschreibung
Zusammenfassung:This most ethereal of cascades: Water‐resistant single isolated Lewis acids within the framework of molecular sieves act as excellent general catalysts for the synthesis of ethers (see scheme). On this basis, an environmentally friendly process has been developed for the preparation of fine chemicals that involves a one‐pot Meerwein–Ponndorf–Verley reduction/etherification cascade.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200604018