[Mn(tmc)(O2)]+: A Side-On Peroxido Manganese(III) Complex Bearing a Non-Heme Ligand

[Mn(tmc)(O2)]+: A Side-On Peroxido Manganese(III) Complex Bearing a Non-Heme Ligand

On the side: The crystal structure of a peroxido MnIII complex bearing a non‐heme ligand shows that the peroxide ligand is bound to a manganese ion symmetrically in a side‐on η2 fashion. The complex is capable of deformylating aldehydes by a nucleophilic reaction but not capable of oxygenating subst...

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Veröffentlicht in:Angewandte Chemie International Edition 2007-01, Vol.46 (3), p.377-380
Hauptverfasser: Seo, Mi Sook, Kim, Ja Young, Annaraj, Jamespandi, Kim, Youngmee, Lee, Yong-Min, Kim, Sung-Jin, Kim, Jinheung, Nam, Wonwoo
Format: Artikel
Sprache:eng
Schlagworte:
aldehyde deformylation
bioinorganic chemistry
Biomimetics
Cyclohexanes - chemistry
enzyme models
Formates - chemistry
Heme - chemistry
Kinetics
Ligands
manganese
Manganese - chemistry
Models, Molecular
Molecular Structure
Organometallic Compounds - chemistry
OO activation
Peroxides - chemistry
Spectrum Analysis
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Zusammenfassung:On the side: The crystal structure of a peroxido MnIII complex bearing a non‐heme ligand shows that the peroxide ligand is bound to a manganese ion symmetrically in a side‐on η2 fashion. The complex is capable of deformylating aldehydes by a nucleophilic reaction but not capable of oxygenating substrates by an electrophilic reaction. tmc=1,4,8,11‐tetramethyl‐1,4,8,11‐tetraazacyclotetradecane.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200603414