Viologen-Based Redox-Active Ionic Liquid Crystals Forming Columnar Phases

Viologens possessing three alkoxy chains at each terminal self-organize into columnar liquid-crystalline phases through nanophase segregation and electrostatic interactions. These viologens are redox-active and susceptible to two consecutive electrochemical reductions.

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Veröffentlicht in:Organic letters 2007-10, Vol.9 (21), p.4271-4274
Hauptverfasser: Tanabe, Kana, Yasuda, Takuma, Yoshio, Masafumi, Kato, Takashi
Format: Artikel
Sprache:eng
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Zusammenfassung:Viologens possessing three alkoxy chains at each terminal self-organize into columnar liquid-crystalline phases through nanophase segregation and electrostatic interactions. These viologens are redox-active and susceptible to two consecutive electrochemical reductions.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol701741e