Phosphorus−Carbon Bond Formation by Lewis Acid Catalyzed/Mediated Addition of Silylphosphines

Phosphorus−Carbon Bond Formation by Lewis Acid Catalyzed/Mediated Addition of Silylphosphines

Triethylaluminum-catalyzed/mediated addition of a silylphosphine to aldehydes and epoxides is described. Organophosphines containing a silyloxy group at the α- or β-position on the alkyl substituent are successfully prepared in good yields.

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Veröffentlicht in:Journal of organic chemistry 2007-09, Vol.72 (20), p.7798-7800
Hauptverfasser: Hayashi, Minoru, Matsuura, Yutaka, Nishimura, Yasunobu, Yamasaki, Toshikazu, Imai, Yoshito, Watanabe, Yutaka
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Organic chemistry
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Zusammenfassung:Triethylaluminum-catalyzed/mediated addition of a silylphosphine to aldehydes and epoxides is described. Organophosphines containing a silyloxy group at the α- or β-position on the alkyl substituent are successfully prepared in good yields.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo701330q