Mononuclear metavanadate catalyses gas phase oxidation of methanol to formaldehyde employing dioxygen as the terminal oxidant

Mononuclear metavanadate catalyses gas phase oxidation of methanol to formaldehyde employing dioxygen as the terminal oxidant

Multistage mass spectrometry experiments reveal a sequence of gas phase reactions for the oxidation of methanol to formaldehyde with a mononuclear oxo vanadate anion as the catalyst and dioxygen as the terminal oxidant.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-01 (43), p.4503-4505
Hauptverfasser: Waters, Tom, Khairallah, George N, Wimala, Samantha A S Y, Ang, Yien C, O'Hair, Richard A J, Wedd, Anthony G
Format: Artikel
Sprache:eng
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Zusammenfassung:Multistage mass spectrometry experiments reveal a sequence of gas phase reactions for the oxidation of methanol to formaldehyde with a mononuclear oxo vanadate anion as the catalyst and dioxygen as the terminal oxidant.
ISSN:1359-7345
1364-548X
DOI:10.1039/b612384h