Magnetically Recyclable Nanocomposite Catalyst for Olefin Epoxidation

“Attractive” catalyst: Molybdenum oxide nanoparticles have been incorporated into a mesoporous silica shell and coated on silica‐coated magnetite nanoparticles for use as a magnetically separable heterogeneous epoxidation catalyst. This catalyst, which has a low Mo loading of 1 mol %, can be recycle...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2007-01, Vol.46 (37), p.7039-7043
Hauptverfasser: Shokouhimehr, Mohammadreza, Piao, Yuanzhe, Kim, Jaeyun, Jang, Youngjin, Hyeon, Taeghwan
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Sprache:eng
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Zusammenfassung:“Attractive” catalyst: Molybdenum oxide nanoparticles have been incorporated into a mesoporous silica shell and coated on silica‐coated magnetite nanoparticles for use as a magnetically separable heterogeneous epoxidation catalyst. This catalyst, which has a low Mo loading of 1 mol %, can be recycled and reused six times in the epoxidation of cis‐cyclooctene with no major loss of activity (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200702386