Unprecedented Formation of a Rhodium Cluster Triggered by Rhodium-Fastened N-Confused Gable Porphyrin

Unprecedented Formation of a Rhodium Cluster Triggered by Rhodium-Fastened N-Confused Gable Porphyrin

Thermal reaction of N-confused porphyrin (NCP) with [RhCl(CO)2]2 caused unprecedented formation of tetranuclear rhodium complex Rh4(NCP)2(CO)4 having a gable-porphyrin-type structure, where two porphyrin π systems were electronically connected by the rhodium cluster.

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Veröffentlicht in:Inorganic chemistry 2006-12, Vol.45 (26), p.10428-10430
Hauptverfasser: Toganoh, Motoki, Niino, Teppei, Maeda, Hiromitsu, Andrioletti, Bruno, Furuta, Hiroyuki
Format: Artikel
Sprache:eng
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Zusammenfassung:Thermal reaction of N-confused porphyrin (NCP) with [RhCl(CO)2]2 caused unprecedented formation of tetranuclear rhodium complex Rh4(NCP)2(CO)4 having a gable-porphyrin-type structure, where two porphyrin π systems were electronically connected by the rhodium cluster.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic061741p